发明授权
US07619106B2 Preparation of partially hydrogenated rac-ansa-metallocene complexes
有权
部分氢化的外消旋 - 茂金属络合物的制备
- 专利标题: Preparation of partially hydrogenated rac-ansa-metallocene complexes
- 专利标题(中): 部分氢化的外消旋 - 茂金属络合物的制备
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申请号: US10532523申请日: 2003-10-22
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公开(公告)号: US07619106B2公开(公告)日: 2009-11-17
- 发明人: Hans-Robert-Hellmuth Damrau , Patrik Müller , Valerie Garcia , Christian Sidot , Christian Tellier , Stéphanie Duchiron , Jean-Francois Lelong
- 申请人: Hans-Robert-Hellmuth Damrau , Patrik Müller , Valerie Garcia , Christian Sidot , Christian Tellier , Stéphanie Duchiron , Jean-Francois Lelong
- 申请人地址: DE Wesseling
- 专利权人: Basell Polyolefine GmbH
- 当前专利权人: Basell Polyolefine GmbH
- 当前专利权人地址: DE Wesseling
- 代理商 William R Reid
- 优先权: DE10250025 20021025
- 国际申请: PCT/EP03/11679 WO 20031022
- 国际公布: WO2004/037838 WO 20040506
- 主分类号: C07F17/00
- IPC分类号: C07F17/00 ; B01J31/00 ; C08F4/44
摘要:
The invention relates to a process for preparing hydrogenated or partially hydrogenated, racemic ansa-metallocene complexes by reacting bridged or unbridged transition metal complexes with alkali metal compounds or alkaline earth metal compounds, heating the resulting reaction mixture to a temperature in the range from −78 to 250° C. and at least partially hydrogenating the reaction products in the presence of a suitable catalyst, to the corresponding hydrogenated or partially hydrogenated metallocenes and to their use as catalysts or as a constituent of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
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