发明授权
US07622607B2 Method for purifying (meth)acrylic acid obtained by oxidizing a gaseous substrate
失效
纯化通过氧化气态基质得到的(甲基)丙烯酸的方法
- 专利标题: Method for purifying (meth)acrylic acid obtained by oxidizing a gaseous substrate
- 专利标题(中): 纯化通过氧化气态基质得到的(甲基)丙烯酸的方法
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申请号: US10577168申请日: 2004-10-01
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公开(公告)号: US07622607B2公开(公告)日: 2009-11-24
- 发明人: Michel Fauconet , Denis Laurent
- 申请人: Michel Fauconet , Denis Laurent
- 申请人地址: FR Colombes
- 专利权人: Arkema France
- 当前专利权人: Arkema France
- 当前专利权人地址: FR Colombes
- 代理商 Steven D. Boyd
- 优先权: FR0312906 20031104
- 国际申请: PCT/FR2004/002481 WO 20041001
- 国际公布: WO2005/054171 WO 20050616
- 主分类号: C07C51/42
- IPC分类号: C07C51/42
摘要:
The present invention relates to a method for purifying (meth)acrylic acid obtained by catalytic or redox oxidation of a gaseous substrate constituting propane, propylene, acrolein, isobutane, isobutene, tert-butyl alcohol and/or (meth)acrolein or mixtures thereof by sending the gaseous reaction mixture to the bottom of a countercurrent absorption column (C1) which is supplied at the top with at least one type of hydrophobic heavy solvent, sending the flow (4) from the bottom of column (C1) to a separation column (C2). Column (C1) is operated at a flow rate of heavy solvent of from 3 to 5.6 times the flow rate of the (meth)acrylic acid in the gaseous reaction mixture and the rectifying column used as a separation column (C2) is operated with the feed at the top and without reflux.
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