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US07666810B2 Ziegler-natta catalyst for high temperature polymerization 有权
齐格勒 - 纳塔催化剂用于高温聚合

Ziegler-natta catalyst for high temperature polymerization
Abstract:
A magnesium titanium olefin polymerization procatalyst is prepared by A) reacting a diorganomagnesium compound with a source of active chlorine, (with the proviso that the amount of chlorine is insufficient to completely convert the diorganomagnesium to magnesium dichloride); then B) removing unreacted diorganomagnesium from the reaction product; then depositing a tetravalent titanium species on the reaction product. This procatalyst is highly active for the solution polymerization of olefins when combined with a cocatalyst.
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