发明授权
- 专利标题: Copolymers containing nanoparticles
- 专利标题(中): 含纳米颗粒的共聚物
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申请号: US11722567申请日: 2005-12-22
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公开(公告)号: US07674868B2公开(公告)日: 2010-03-09
- 发明人: Oliver Minge , Richard Weidner , Frank Sandmeyer , Hans-Peter Weitzel
- 申请人: Oliver Minge , Richard Weidner , Frank Sandmeyer , Hans-Peter Weitzel
- 申请人地址: DE Munich
- 专利权人: Wacker Chemie AG
- 当前专利权人: Wacker Chemie AG
- 当前专利权人地址: DE Munich
- 代理机构: Brooks Kushman P.C.
- 优先权: DE102005000824 20050105
- 国际申请: PCT/EP2005/013919 WO 20051222
- 国际公布: WO2006/072408 WO 20060713
- 主分类号: C08F230/08
- IPC分类号: C08F230/08
摘要:
The invention provides copolymers of ethylenically unsaturated monomers and of ethylenically functionalized nanoparticles in the form of their aqueous polymer dispersions or water-redispersible polymer powders, obtainable by means of free-radically initiated polymerization in an aqueous medium and, if desired, subsequent drying of the resultant polymer dispersion, ofA) one or more monomers from the group consisting of vinyl esters, (meth)acrylic esters, vinylaromatics, olef ins, 1,3-dienes, vinyl ethers and vinyl halides and, if desired, further monomers copolymerizable therewith, in the presence ofB) at least one particle P having an average diameter of ≦1000 nm, which is functionalized with ethylenically unsaturated, free-radically polymerizable groups, characterized in thatB2) particles P used are one or more from the group of metal oxides and semimetal oxides, and/orB2) particles P used are silicone resins composed of repeating units of the general formula [R4(p+Z)SiO(4−p−Z)/2] (II), where for at least 20 mol % of the respective silicone resin p+z=0, 1 or 3,and where B1) and B2) are each functionalized with one or more α-organosilanes of the general formula (R1O)3−(R2)nSi—(CR32)—X (I), where X is a radical having 2 to 20 hydrocarbon atoms and containing an ethylenically unsaturated group.
公开/授权文献
- US20080146743A1 Copolymers Containing Nanoparticles 公开/授权日:2008-06-19
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