发明授权
- 专利标题: Process for producing lower olefins from methanol or dimethylether
- 专利标题(中): 从甲醇或二甲醚生产低级烯烃的方法
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申请号: US11503913申请日: 2006-08-15
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公开(公告)号: US07692056B2公开(公告)日: 2010-04-06
- 发明人: Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Xiaofeng Chen
- 申请人: Zaiku Xie , Juntao Liu , Weimin Yang , Siqing Zhong , Xiaofeng Chen
- 申请人地址: CN Shanghai
- 专利权人: Shanghai Research Institute of Petrochemical Technology Sinopec
- 当前专利权人: Shanghai Research Institute of Petrochemical Technology Sinopec
- 当前专利权人地址: CN Shanghai
- 代理机构: Birch, Stewart, Kolasch & Birch, LLP.
- 优先权: CN200510028809 20050815
摘要:
The present invention provides a process for producing lower olefins from methanol or dimethyl ether. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including high operation temperature, low yield and selectivity of lower olefins as the target products, and poor stability and short regeneration period of catalyst. The present process, which is carried out under the conditions of catalytic cracking methanol and dimethyl ether and the presence of diluting gas, and adopts as a feedstock methanol, dimethyl ether or their mixture, comprises the steps of: a) letting the feedstock firstly enter a first reaction zone to contact with a first crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a first reaction effluent containing lower olefins; b) letting the first reaction effluent enter in turn at least one second reaction zone to contact with a second crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a second reaction effluent containing lower olefins; and c) separating lower olefins from the second reaction effluent; wherein the weight ratio of the diluting gas to the feedstock is 0.01-6:1, while controlling the reaction conditions.
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