A method for activating a state transition of a liquid crystal in a liquid crystal display is provided. The liquid crystal display has a first substrate, a second substrate and plural pixel structures, wherein the liquid crystal is sandwiched between the first substrate and the second substrate and each of the plural pixel structures has a transistor having a first electrode and a second electrode. The method including steps of: providing a first potential difference between the first electrode and the second electrode to generate a first electric field; providing a second potential difference between the first substrate and the second substrate to generate a second electric field; and transitioning the liquid crystal from a non-display alignment state to a display alignment state by the first and the second electric fields.