发明授权
- 专利标题: Method for the preparation of linear alpha-olefins and reactor system therefore with improved disposal of high molecular weight oligomers
- 专利标题(中): 因此,制备线性α-烯烃和反应器系统的方法可改进处理高分子量低聚物
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申请号: US11989831申请日: 2006-06-13
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公开(公告)号: US07723557B2公开(公告)日: 2010-05-25
- 发明人: Peter Fritz , Heinz Bölt , Stefan Glanz , Richard Schneider , Talal Ali , Sultan Al-Otaibi , Fuad Mosa
- 申请人: Peter Fritz , Heinz Bölt , Stefan Glanz , Richard Schneider , Talal Ali , Sultan Al-Otaibi , Fuad Mosa
- 申请人地址: SA Riyadh DE Munich
- 专利权人: Saudi Basic Industries Corporation,Linde AG
- 当前专利权人: Saudi Basic Industries Corporation,Linde AG
- 当前专利权人地址: SA Riyadh DE Munich
- 代理机构: Kramer Levin Naftalis & Frankel LLP
- 优先权: EP05016524 20050729
- 国际申请: PCT/EP2006/005641 WO 20060613
- 国际公布: WO2007/016992 WO 20070215
- 主分类号: C07C7/00
- IPC分类号: C07C7/00
摘要:
The present invention relates to a method for processing high molecular weight oligomer waste products formed during the production of linear alpha-olefins by oligomerization of ethylene in a reactor in the presence of a solvent and a catalyst, characterized in that the high molecular weight oligomers are separated in a separation unit from a product stream of the reactor comprising the solvent, the catalyst, linear alpha-olefins and high molecular weight oligomers having a solidification temperature in the range of about 60-100° C., then diluted with a dilution medium and heated to about 130° C. to about 200° C., the diluted high molecular weight oligomers are then transferred to a disposal device, wherein at least some of the dilution medium may be recovered and recycled for addition to the dilution medium.
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