A fire-blocking paper (22, 52) is adapted for incorporation into a fire-barrier film laminate (16, 46) for use in thermal and acoustical insulation systems (10, 40), such as, but not limited to, those used in commercial aircraft. The fire-blocking inorganic fiber paper (22, 52) can be laminated to a flame resistant film (24a, 24b, 54a, 54b). The fire-blocking paper (22, 52) may include inorganic bio-soluble fiber, chopped glass non-respirable fibers, organic reinforcing fibers, organic binder, and inorganic binder or filler; and, optionally or refractory ceramic fibers.