A pixel structure including an active device, a first pixel electrode, a second pixel electrode, a coupling line, a common electrode, and a liquid crystal layer is provided. The first pixel electrode and the second pixel electrode have a plurality of sets of stripped electrode patterns extending along different directions, respectively, and the first pixel electrode is electrically insulated from the second pixel electrode. The coupling line is disposed under the first and the second pixel electrode and electrically insulated from the second pixel electrode. The first pixel electrode is electrically connected to the active device through the coupling line. The common electrode is disposed over the first and the second pixel electrode. The liquid crystal layer is disposed between the common electrode and the first and second pixel electrodes. Moreover, the liquid crystal layer has two polymer layers and a liquid crystal molecule layer disposed between the polymer layers.