发明授权
US07824455B2 High activity water gas shift catalysts based on platinum group metals and cerium-containing oxides
有权
基于铂族金属和含铈氧化物的高活性水煤气变换催化剂
- 专利标题: High activity water gas shift catalysts based on platinum group metals and cerium-containing oxides
- 专利标题(中): 基于铂族金属和含铈氧化物的高活性水煤气变换催化剂
-
申请号: US10617146申请日: 2003-07-10
-
公开(公告)号: US07824455B2公开(公告)日: 2010-11-02
- 发明人: Anca Faur-Ghenciu , Nathan Edward Trusty , Mark Robert Feaviour , Jessica Grace Reinkingh , Phillip Shady , Paul Joseph Andersen
- 申请人: Anca Faur-Ghenciu , Nathan Edward Trusty , Mark Robert Feaviour , Jessica Grace Reinkingh , Phillip Shady , Paul Joseph Andersen
- 申请人地址: US MI Detroit
- 专利权人: General Motors Corporation
- 当前专利权人: General Motors Corporation
- 当前专利权人地址: US MI Detroit
- 代理机构: Dinsmore & Shohl LLP
- 主分类号: C01B3/24
- IPC分类号: C01B3/24 ; C10J3/46
摘要:
A method of reducing the amount of carbon monoxide in process fuel gas in a feed stream for a fuel cell. The method includes introducing a hydrocarbon feed stream into a primary reactor and reacting the hydrocarbon feed stream in effective contact with a reforming catalyst forming primary reactor products containing hydrogen, carbon monoxide, carbon dioxide, and methane; placing a high activity water gas shift catalyst system into a water gas shift converter, introducing the primary reactor products into the water gas shift converter in effective contact with the high activity water gas shift catalyst system, and reacting the carbon monoxide and water to form carbon dioxide and hydrogen using a water gas shift reaction forming the feed stream for the fuel cell; and introducing the feed stream into the fuel cell. The high water gas shift catalyst system includes a noble metal, a support comprising a mixed metal oxide of cerium oxide and at least one of zirconium oxide or lanthanum oxide. A promoter of yttrium, an alkali metal, or alkaline earth metal can be included. A support dopant can also be included.
公开/授权文献
信息查询