Invention Grant
- Patent Title: Process for the production of aqueous binder latices
- Patent Title (中): 生产含水粘合剂胶乳的方法
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Application No.: US11273834Application Date: 2005-11-15
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Publication No.: US07825173B2Publication Date: 2010-11-02
- Inventor: Tonnie Willems , Matthieu Barrere , Kok-Far Lee , Frank Tessari , Stefan Wiggershaus , Paul P. Bruylants , Eric C. Houze
- Applicant: Tonnie Willems , Matthieu Barrere , Kok-Far Lee , Frank Tessari , Stefan Wiggershaus , Paul P. Bruylants , Eric C. Houze
- Applicant Address: US DE Wilmington
- Assignee: E.I. du Pont de Nemours and Company
- Current Assignee: E.I. du Pont de Nemours and Company
- Current Assignee Address: US DE Wilmington
- Agent Sudhir G. Deshmukh
- Main IPC: C08F265/02
- IPC: C08F265/02 ; C08F265/06 ; C09D151/00

Abstract:
A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a mixture A of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture A of 10 to 100 mg of KOH/g and 0.5 to 5 wt. % of at least one olefinically polyunsaturated monomer, in the aqueous phase, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one mixture B of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture B or each of the mixtures B of 0 to below 5 mg of KOH/g, at least one monomer with at least one hydroxyl group in a proportion corresponding to a hydroxyl value of mixture B or each of the mixtures B of 0 to below 5 mg of KOH/g and at least one olefinically polyunsaturated monomer in a proportion of 0.5 to 5 wt. %, relative to mixture B or each of the mixtures B, in the presence of the product obtained in process step 2), wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt. % of the monomers of mixture A have been polymerized to completion.
Public/Granted literature
- US20060247357A1 Process for the production of aqueous binder latices Public/Granted day:2006-11-02
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