Provided are a communication system using ZigBee to coordinate communication terminals, to transmit and receive data via a coordinator, and to perform a binding operation of setting channels and personal area network (PAN) identifications (IDs) of the communication terminals using only a remote controller when forming a ZigBee communication network between a home appliance and a remote controller, and a method of controlling the same. The communication system which forms a communication network between communication terminals, includes: a ZigBee coordinator disposed at one of the communication terminals, coordinating the communication terminals, and transmitting and receiving data; and a ZigBee device disposed at another one of the plurality of communication terminals and forming a ZigBee communication network through communication with the ZigBee coordinator, wherein an inputting unit for setting channels and PAN IDs of the ZigBee coordinator is provided at the communication terminal in which the ZigBee device is disposed.