发明授权
US07846325B2 Process for the removal of COS and H2S from a synthesis gas stream comprising H2S and COS
有权
从包含H 2 S和COS的合成气流中除去COS和H 2 S的方法
- 专利标题: Process for the removal of COS and H2S from a synthesis gas stream comprising H2S and COS
- 专利标题(中): 从包含H 2 S和COS的合成气流中除去COS和H 2 S的方法
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申请号: US11632883申请日: 2005-07-22
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公开(公告)号: US07846325B2公开(公告)日: 2010-12-07
- 发明人: Robert Martijn Van Hardeveld , Rudolf Henri Max Herold , Adriaan Johannes Kodde , Thijme Last , Cornelis Jacobus Smit
- 申请人: Robert Martijn Van Hardeveld , Rudolf Henri Max Herold , Adriaan Johannes Kodde , Thijme Last , Cornelis Jacobus Smit
- 申请人地址: US TX Houston
- 专利权人: Shell Oil Company
- 当前专利权人: Shell Oil Company
- 当前专利权人地址: US TX Houston
- 代理商 Leonard P. Miller; Charles W. Stewart
- 优先权: EP04254366 20040722
- 国际申请: PCT/EP2005/053563 WO 20050722
- 国际公布: WO2006/008317 WO 20060126
- 主分类号: C01D17/00
- IPC分类号: C01D17/00 ; B01D53/86 ; C07C27/00
摘要:
The invention provides a process for the removal of COS and H2S from a synthesis gas stream comprising COS and H2S, the process having the steps of: removing H2S from a feed synthesis gas stream with a first solid adsorbent to obtain a first synthesis gas stream, converting COS in the first synthesis gas stream to H2S by contacting the first synthesis gas stream with a COS-hydrolysing catalyst in the presence of water in a hydrolysis zone to obtain a second synthesis gas stream depleted of COS and enriched in H2S; and removing H2S from the second synthesis gas stream by contacting the second synthesis gas stream with a second solid adsorbent in a H2S removal zone to obtain a third synthesis gas stream depleted of H2S and depleted of COS to very low levels.