发明授权
- 专利标题: Phase boundary processes for preparing polycarbonates
- 专利标题(中): 制备聚碳酸酯的相边界法
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申请号: US12398243申请日: 2009-03-05
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公开(公告)号: US07847051B2公开(公告)日: 2010-12-07
- 发明人: Wolfgang Ebert , Christian Kords , Rolf Bachmann , Lars Obendorf , Johan Vanden Eynde , Bert Ruytinx , Johann Seeba
- 申请人: Wolfgang Ebert , Christian Kords , Rolf Bachmann , Lars Obendorf , Johan Vanden Eynde , Bert Ruytinx , Johann Seeba
- 申请人地址: DE Leverkusen
- 专利权人: Bayer MaterialScience AG
- 当前专利权人: Bayer MaterialScience AG
- 当前专利权人地址: DE Leverkusen
- 代理机构: Connolly Bove Lodge & Hutz LLP
- 优先权: DE102008012613 20080305
- 主分类号: C08G64/00
- IPC分类号: C08G64/00 ; C08G63/18
摘要:
Continuous processes for preparing polycarbonates having a weight average molecular weight Mw, of 15,000 to 200,000 g/mol, the processes comprising reacting a dihydroxydiarylalkane and phosgene in the presence of a catalyst in a phase boundary process comprising: continuously dispersing in a disperser an organic phase comprising at least a portion of the phosgene and a solvent suitable for the polycarbonate and an aqueous phase comprising the dihydroxydiarylalkane, water and an alkali solution present in an amount of 1.5 to 2.5 moles per mole of the dihydroxydiarylalkane, to form a mixture; reacting the mixture in a first reactor with a residence time of less than 0.5 seconds; further reacting the mixture in a second reactor with addition of further alkali solution and, optionally, a chain terminator; and effecting further condensation in a third reactor with addition of further alkali solution and, optionally, a chain terminator, in the presence of the catalyst.
公开/授权文献
- US20090275709A1 PHASE BOUNDARY PROCESSES FOR PREPARING POLYCARBONATES 公开/授权日:2009-11-05
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