发明授权
- 专利标题: Integrated process for the production of vinyl acetate from acetic acid via ethylene
- 专利标题(中): 通过乙烯从乙酸生产乙酸乙烯酯的综合方法
-
申请号: US12291949申请日: 2008-11-14
-
公开(公告)号: US07855303B2公开(公告)日: 2010-12-21
- 发明人: Victor J. Johnston , Laiyuan Chen , James H. Zink , Josefina T. Chapman , Barbara F. Kimmich , Deborah R. Repman
- 申请人: Victor J. Johnston , Laiyuan Chen , James H. Zink , Josefina T. Chapman , Barbara F. Kimmich , Deborah R. Repman
- 申请人地址: US TX Dallas
- 专利权人: Celanese International Corporation
- 当前专利权人: Celanese International Corporation
- 当前专利权人地址: US TX Dallas
- 主分类号: C07C67/00
- IPC分类号: C07C67/00 ; C07C67/05
摘要:
This invention provides an integrated two stage economical process for the production of vinyl acetate monomer (VAM) from acetic acid in the vapor phase. First, acetic acid is selectively hydrogenated over a hydrogenating catalyst composition to form ethylene either in a single reactor zone or in a dual rector zone wherein the intermediate hydrogenated products are either dehydrated and/or cracked to form ethylene. In a subsequent second stage so formed ethylene is reacted with molecular oxygen and acetic acid over a suitable catalyst to form VAM. In an embodiment of this invention reaction of acetic acid and hydrogen over a hydrogenation catalyst and subsequent reaction over a dehydration catalyst selectively produces ethylene, which is further mixed with acetic acid and molecular oxygen and reacted over a supported palladium/gold/potassium catalyst.
公开/授权文献
信息查询