Disclosed is a method of dynamical frequency selecting for a basic service set established by a main wireless device in a wireless local area network. The method comprises steps of a determining step for determining whether a new channel to be used by said BSS is needed; a scanning step conducted by said main wireless device for scanning all channels based on a random priority to detect whether other adjacent BSSs are existing and performing DFS concurrently; a measuring step conducted by said main wireless device based on the scanning result for existing operational BSSs for measuring channel quality of a plurality of channels; selecting one channel based on the channel quality parameters. The present invention advantageously provides a dynamic frequency selection method without any modification for the IEEE 802.11 standard, or any requirement for the implementation of the wireless stations.