发明授权
- 专利标题: Process for producing lower olefins under negative pressure
- 专利标题(中): 在负压下生产低级烯烃的方法
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申请号: US11990401申请日: 2006-08-09
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公开(公告)号: US07875756B2公开(公告)日: 2011-01-25
- 发明人: Zaiku Xie , Juntao Liu , Siqing Zhong , Wenwei Wu
- 申请人: Zaiku Xie , Juntao Liu , Siqing Zhong , Wenwei Wu
- 申请人地址: CN Beijing CN Shanghai
- 专利权人: China Petroleum & Chemical Corporation,Shanghai Research Institute of Petrochemical Technology Sinopec
- 当前专利权人: China Petroleum & Chemical Corporation,Shanghai Research Institute of Petrochemical Technology Sinopec
- 当前专利权人地址: CN Beijing CN Shanghai
- 代理机构: Birch, Stewart, Kolasch & Birch, LLP
- 优先权: CN200510028810 20050815
- 国际申请: PCT/CN2006/002013 WO 20060809
- 国际公布: WO2007/019787 WO 20070222
- 主分类号: C07C4/06
- IPC分类号: C07C4/06
摘要:
A process for producing lower olefins is disclosed. The technical problem is to overcome the defects presented in the prior art including high reaction pressure, high reaction temperature, low yield and selectivity of lower olefins as the target products, poor stability and short life of catalyst, and limited suitable feedstocks. The disclosed process, which is carried out under the conditions of catalytic cracking olefins and adopts as a feedstock an olefins-enriched mixture containing one or more C4 or higher olefins and optionally an organic oxygenate compound, comprises the steps of: a) letting the feedstock contact with a crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a reaction effluent containing lower olefins; and b) separating lower olefins from the reaction effluent; wherein, the reaction pressure is from −0.1 MPa to
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