发明授权
- 专利标题: Process for producing polybutadiene rubber and rubber composition
- 专利标题(中): 生产聚丁二烯橡胶和橡胶组合物的方法
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申请号: US10596757申请日: 2005-12-20
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公开(公告)号: US07884155B2公开(公告)日: 2011-02-08
- 发明人: Naomi Okamoto , Mitsuharu Anbe , Jyun Yamashita , Tetsuji Nakajima , Takashi Kitamura , Osamu Kimura , Takashi Wada
- 申请人: Naomi Okamoto , Mitsuharu Anbe , Jyun Yamashita , Tetsuji Nakajima , Takashi Kitamura , Osamu Kimura , Takashi Wada
- 申请人地址: JP Yamaguchi
- 专利权人: Ube Industries, Ltd.
- 当前专利权人: Ube Industries, Ltd.
- 当前专利权人地址: JP Yamaguchi
- 代理机构: Panitch Schwarze Belisario & Nadel LLP
- 优先权: JP2004-367702 20041220; JP2005-010687 20050118; JP2005-010688 20050118; JP2005-010689 20050118; JP2005-010690 20050118; JP2005-010691 20050118; JP2005-010692 20050118; JP2005-010693 20050118; JP2005-177170 20050617; JP2005-177171 20050617; JP2005-177172 20050617
- 国际申请: PCT/JP2005/023377 WO 20051220
- 国际公布: WO2006/054808 WO 20060526
- 主分类号: C08K3/34
- IPC分类号: C08K3/34
摘要:
A process for producing a vinyl-cis-polybutadiene rubber, including mixing (A) vinyl-cis-polybutadiene obtained by (1) a step of adding a cis-1,4-polymerization catalyst obtainable from an organoaluminum compound and a soluble cobalt compound to a mixture containing 1,3-butadiene and a hydrocarbon-based organic solvent as the major components and having an adjusted water content, thereby subjecting the 1,3-butadiene to cis-1,4-polymerization and subsequently, (2) a step of making a catalyst obtainable from a soluble cobalt compound, an organoaluminum compound represented by the general formula, AlR3 (wherein R represents an alkyl group having from 1 to 6 carbon atoms, a phenyl group, or a cycloalkyl group), and carbon disulfide present in the resulting polymerization reaction mixture, thereby subjecting the 1,3-butadiene to 1,2-polymerization; and (B) cis-polybutadiene obtained by a step of adding the foregoing cis-1,4-polymerization catalyst, thereby subjecting the 1,3-butadiene to cis-1,4-polymerization and a rubber composition containing the resulting rubber.
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