- 专利标题： Method for producing optically active aziridine compounds and amine compounds as well as complexes and their intermediates used in this method
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申请号： US12654825申请日： 2010-01-05
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公开(公告)号： US07897819B2公开(公告)日： 2011-03-01
- 发明人: Tsutomu Katsuki , Kazufumi Omura , Tatsuya Uchida , Ryo Irie
- 申请人： Tsutomu Katsuki , Kazufumi Omura , Tatsuya Uchida , Ryo Irie
- 申请人地址： JP Kawaguchi-Shi
- 专利权人： Japan Science and Technology Agency
- 当前专利权人： Japan Science and Technology Agency
- 当前专利权人地址： JP Kawaguchi-Shi
- 代理机构： Oliff & Berridge, PLC
- 优先权： JP2004-197255 20040702
- 主分类号： C07C47/23
- IPC分类号： C07C47/23 ; C07C43/30
摘要：
This invention provides a method for producing an optically active aziridine compound or amine compound, which uses as a catalyst a Ru(salen)(CO) complex represented by the following formula (I) or its enantiomer having a high stability, in a high turnover number (TON) and a high enantioselectivity. In the formula (I), Ar is represented by the following formula (VI) or (VII), wherein in the formula (VI), Xs are independently a halogen or a halogenated alkyl group and R1 and R2s are independently hydrogen or an alkyl group or a trialkylsilyl group having a carbon number of 1-4, and in the formula (VII), R3 is a bulky group.
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