发明授权
- 专利标题: Low melting polyester polymers
- 专利标题(中): 低熔聚酯聚合物
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申请号: US11018119申请日: 2004-12-21
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公开(公告)号: US07935399B2公开(公告)日: 2011-05-03
- 发明人: Michael Paul Ekart , Frederick Leslie Colhoun , Mary Therese Jernigan , Stephen Weinhold , Rodney Scott Armentrout
- 申请人: Michael Paul Ekart , Frederick Leslie Colhoun , Mary Therese Jernigan , Stephen Weinhold , Rodney Scott Armentrout
- 申请人地址: MX Nuevo Leon
- 专利权人: Grupo Petrotemex, S.A. de C.V.
- 当前专利权人: Grupo Petrotemex, S.A. de C.V.
- 当前专利权人地址: MX Nuevo Leon
- 代理机构: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- 主分类号: B32B1/02
- IPC分类号: B32B1/02 ; B32B1/08
摘要:
A bulk of polyester polymer particles comprising polyester polymer comprising greater than 75% virgin polyester polymer, the particles having: A) an It.V. of at least 0.72 dl/g, and B) 10 ppm or less of residual acetaldehyde; and C) at least two melting peaks, wherein one of said at least two melting peaks is a low peak melting point within a range of 140° C. to 220° C. and having a melting endotherm area of at least the absolute value of 1 J/g. The particles may also have a degree of crystallinity within a range of 20% and a maximum degree of crystallinity Tcmax defined by the equation: Tcmax=50%−CA−OH where CA is the total mole % of all carboxylic acid residues other than terephthalic acid residues, based on 100 mole % of carboxylic acid residues, and OH is the total mole % of all hydroxyl functional compound residues other than ethylene glycol residues, based on 100 mole % of hydroxyl functional compounds residues. The preforms and bottles made from these particles can be obtained by melt processing these particles at either lower overall power, faster screw speeds, lower residence time, or lower overall cycle time to thereby reduce the level of residual acetaldehyde generated in the melt.
公开/授权文献
- US20060046004A1 Low melting polyester polymers 公开/授权日:2006-03-02
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