Amines or ammonia and amines may be used to enhance recovery of heavy hydrocarbons. The amines or ammonia and amines alone or with water, steam or an oil solvent are combined with the heavy hydrocarbons to promote the transport of the heavy hydrocarbons. The amines or ammonia and amines may be injected downhole or admixed with heavy hydrocarbon containing ore on the surface, optionally with water or steam. Ammonia may be used alone with high quality steam.