A direct methanol fuel cell (DMFC) comprising: a membrane electrode assembly (MEA) including an anode, a cathode, and a membrane disposed therebetween; a spacer surrounding the anode, having supply holes to supply methanol to the anode; and a flow control member to control the supply of the methanol. The flow control member includes a porous support and/or a methanol transmissive layer. The methanol transmissive layer comprises a fluorine polymer, a hydrocarbon polymer, or a combination thereof.