发明授权
US07964677B2 Method of changing between incompatible polymerization catalysts in a gas-phase fluidized-bed reactor 有权
在气相流化床反应器中改变不相容的聚合催化剂的方法

  • 专利标题: Method of changing between incompatible polymerization catalysts in a gas-phase fluidized-bed reactor
  • 专利标题(中): 在气相流化床反应器中改变不相容的聚合催化剂的方法
  • 申请号: US12085079
    申请日: 2006-11-10
  • 公开(公告)号: US07964677B2
    公开(公告)日: 2011-06-21
  • 发明人: Shahram MihanRainer Karer
  • 申请人: Shahram MihanRainer Karer
  • 申请人地址: DE Wesseling
  • 专利权人: Basell Polyolefine GmbH
  • 当前专利权人: Basell Polyolefine GmbH
  • 当前专利权人地址: DE Wesseling
  • 代理机构: Dilworth IP, LLC
  • 优先权: DE102005056775 20051128
  • 国际申请: PCT/EP2006/010814 WO 20061110
  • 国际公布: WO2007/059867 WO 20070531
  • 主分类号: C08F2/34
  • IPC分类号: C08F2/34 C08F4/78
Method of changing between incompatible polymerization catalysts in a gas-phase fluidized-bed reactor
摘要:
Method of changing from a polymerization using a first catalyst to a polymerization using a second catalyst which is incompatible with the first catalyst in a gas-phase reactor, which comprises the steps a) stopping of the polymerization reaction using the first catalyst, b) flushing of the reactor under polymerization conditions with at least one deactivating agent comprising a volatile constituent and a nonvolatile constituent in a weight ratio of from 0.1 to 1000, c) introduction of the second catalyst into the reactor and d) continuation of the polymerization using the second catalyst.
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