An apparatus for molding and vulcanization of tyres for vehicle wheels includes a vulcanization press and a vulcanization mold associated with the press. The apparatus includes a pair of plates and a plurality of mold sectors that are mutually movable between an open condition and a closed condition; at least one plurality of sector carriers designed to support the mold sectors and movable together with the sectors; and a plurality of guide means on which the plurality of sector carriers slide for movement of the mold sectors from the closed condition to the open condition and vice versa, at least part of the sector carriers having at least one spring device designed to exert a thrust action adapted to ensure sliding of the sector carrier on the guide element in a substantially parallel direction.