An electrochemical fuel cell includes a membrane-electrode assembly (MEA) having a cathode face and an anode face. The MEA is between a cathode fluid flow field plate and an anode fluid flow field plate. A diffusion structure is between the MEA and a corresponding fluid flow field plate, which is either the cathode fluid flow field plate or the anode fluid flow field plate. The diffusion structure has a first face in contact with, or adjacent to, the MEA and a second face in contact with, or adjacent to, the corresponding fluid flow field plate. The diffusion structure includes a first layer having a first level of hydrophobicity and a second layer that is hydrophilic. The second layer is adjacent to the corresponding fluid flow field plate, and includes a hydrophilic binder material.