发明授权
US08048960B2 Monovinylidene aromatic polymers comprising sulfanylsilane functionalized elastomeric polymers
有权
包含硫烷基硅烷官能化的弹性体聚合物的单亚乙烯基芳族聚合物
- 专利标题: Monovinylidene aromatic polymers comprising sulfanylsilane functionalized elastomeric polymers
- 专利标题(中): 包含硫烷基硅烷官能化的弹性体聚合物的单亚乙烯基芳族聚合物
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申请号: US12596162申请日: 2008-03-27
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公开(公告)号: US08048960B2公开(公告)日: 2011-11-01
- 发明人: Amaia Montoya-Goni , Jose M. Rego , Evemarie Hamann , Sven K. H. Thiele
- 申请人: Amaia Montoya-Goni , Jose M. Rego , Evemarie Hamann , Sven K. H. Thiele
- 申请人地址: CH Horgen
- 专利权人: Styron Europe GmbH
- 当前专利权人: Styron Europe GmbH
- 当前专利权人地址: CH Horgen
- 代理机构: Brinks Hofer Gilson & Lione
- 国际申请: PCT/US2008/058336 WO 20080327
- 国际公布: WO2008/130782 WO 20081030
- 主分类号: C08F8/00
- IPC分类号: C08F8/00 ; C08L9/00 ; C08L25/02 ; C08K5/00
摘要:
The present invention is a rubber modified monovinylidene aromatic polymer composition where the rubber is a sulfanylsilane chain end modified elastomeric polymer. In the present invention the functionalized rubber provides sufficient grafting levels in standard graft polymerization process technologies to prepare desired rubber particle size distributions and morphologies. Across a range of rubber modified monovinylidene aromatic polymers, it has been found that the use of the modified elastomeric polymers according to the present invention can improve the combinations of resin properties, particularly clarity, surface and physical properties, including both rubber modified monovinylidene aromatic homopolymers (e.g., high impact polystyrene and copolymers (e.g., ABS). The functionalized rubbers have sulfanyl functional groups that provide an optimized reactive grafting site. This ensures that under graft polymerization conditions a monovinylidene aromatic polymer block is formed grafted to the butadiene polymer block. This is particularly desirable to enable the use of polybutadiene homopolymer rubbers which are more cost effectively used in rubber-modified monovinylidene aromatic polymers.
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