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发明授权
US08049024B2 Heterogenized rhodium complexes, methods of their synthesis and application as hydrosilylation catalysts 有权
杂化铑配合物，其合成方法和作为氢化硅烷化催化剂的应用

Heterogenized rhodium complexes, methods of their synthesis and application as hydrosilylation catalysts
摘要：
The subjects of the invention are new heterogenized rhodium complexes, the methods of their synthesis and their application as catalysts for synthesis of organosilicon compounds by hydrosilylation. The subject of the invention are new siloxide rhodium(I) complexes immobilised on the silica surface, of the general formula 1. [(≡SiO)(L)Rh(diene)] The second subject of the invention is the method of synthesis of the new rhodium complexes of the general formula 1. The third subject of the invention is the method of obtaining the organosilicon compounds in the reaction of hydrosilylation between the selected alkenes or functionalised alkenes containing the terminal C═C bond and the appropriate compounds containing the Si═H bond selected from silanes, (poly)siloxanes and (poly)carbosiloxanes, in the presence of heterogenized rhodium catalysts, of the general formula 1.
摘要（中）：

本发明的主题是新的异质化铑络合物，其合成方法及其作为通过氢化硅烷化合成有机硅化合物的催化剂的应用。 本发明的主题是通式1固定在二氧化硅表面上的新的硅氧烷铑（I）络合物。[（≡SiO）（L）Rh（二烯）]本发明的第二个主题是合成 本发明的第三个主题是在所选择的烯烃或含末端C = C键的官能化烯烃和含有Si的适当化合物之间的氢化硅烷化反应中获得有机硅化合物的方法 在通式1的异构铑催化剂的存在下，选自硅烷，（聚）硅氧烷和（聚）碳硅氧烷的≡H键。

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