A heat-sensitive transfer sheet, containing a substrate, at least one thermal transfer layer containing a thermally transferable dye and a resin, disposed on one surface of the substrate, and a heat-resistant slipping layer disposed on another surface of the substrate, wherein said at least one thermal transfer layer contains at least one kind of polymer type releasing agent having a mass-average molecular weight of 5,000 to 100,000 and also having a fluorine-substituted aliphatic group at a side chain of the polymer, and at least one kind of non-polymer type fluorine-system surfactant.