发明授权
- 专利标题: High shear oxidation of cyclohexane
- 专利标题(中): 环己烷的高剪切氧化
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申请号: US12628795申请日: 2009-12-01
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公开(公告)号: US08088953B2公开(公告)日: 2012-01-03
- 发明人: Abbas Hassan , Aziz Hassan , Gregory G. Borsinger , Krishnan Viswanathan , Rayford G. Anthony
- 申请人: Abbas Hassan , Aziz Hassan , Gregory G. Borsinger , Krishnan Viswanathan , Rayford G. Anthony
- 申请人地址: US TX Houston
- 专利权人: H R D Corporation
- 当前专利权人: H R D Corporation
- 当前专利权人地址: US TX Houston
- 主分类号: C07C45/00
- IPC分类号: C07C45/00 ; C07C35/08
摘要:
Disclosed herein is a method for cyclohexane oxidation. The method comprises a) forming a dispersion comprising liquid cyclohexane and an oxidant gas utilizing a high shear device, wherein the dispersion comprises oxidant gas bubbles with a mean diameter of less than about 5 μm, and wherein the high shear device comprises at least one rotor and at least one stator; and b) hydrogenating the dispersion in the presence of a hydrogenation catalyst to form a product comprising cyclohexanol or cyclohexanone. In some embodiments, the oxidant comprises air, oxygen-enriched air, oxygen, or an oxygen-containing gas. In some embodiments, step a) of the method comprises forming the dispersion in the presence of an oxidation catalyst. Also disclosed herein is a system for oxidizing cyclohexane.
公开/授权文献
- US20100168477A1 HIGH SHEAR OXIDATION OF CYCLOHEXANE 公开/授权日:2010-07-01
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