First and second transmitted optical waves having orthogonal polarization states are combined in a polarization multiplexed optical wave. At an optical receiver, an electrical field of the polarization multiplexed optical wave is measured. A plurality of polarization states of the polarization multiplexed optical wave is determined from the measured electrical field. From the plurality of polarization states, a transform that aligns the orthogonal polarization states of the first and second transmitted optical waves with respect to principal axes of the optical receiver is estimated. The first and second transmitted optical waves are recovered by applying the transform to one of i) the polarization multiplexed optical wave and ii) the measured electrical field of the polarization multiplexed optical wave.