Invention Grant
US08124223B2 Aramid filled polyimides having advantageous thermal expansion properties, and methods relating thereto 失效
具有有利的热膨胀性能的芳族聚酰胺填充的聚酰亚胺及其相关的方法

Aramid filled polyimides having advantageous thermal expansion properties, and methods relating thereto
Abstract:
The invention is directed to polyimide based adhesives having a coefficient of thermal expansion (“CTE”) equal to or below 50 ppm/° C. The adhesives of the present invention contain a polyimide base polymer present in the overall adhesive in an amount from 25 to 95 weight percent. The polyimide base polymer has a glass transition temperature (“Tg”) in a range of from about 150 to about 300° C. and typically has a coefficient of thermal expansion above 50 ppm/° C. The polyimide based adhesives of the invention also contain an aramid micro fiber filler in an amount from 5 to 75 weight percent, based upon the total weight of the polyimide based adhesive. The fiber filler can be used to lower CTE of the overall adhesive to match (or nearly match) the CTE of other materials like metal, silicon wafers, other polymers (including polyimide) and the like.
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