The present invention relates to a method for liquid crystal display element without substrates, which comprises applying a release agent to assisting substrates in the process of producing the liquid crystal display so that the assembled liquid crystal display element can be separated from the assisting substrates and the liquid crystal display element is obtained, wherein said release agent comprises (a) 2-20 wt % of compounds selected from the group consisting of silicone, fluorine compounds and mixtures thereof; (b) 0.01-0.6 wt % of release modifier; and (c) a solvent as a complement to 100 wt %.