A method of controlling an uninterruptible power supply apparatus (UPS) is provided. The UPS apparatus includes at least an AC input voltage, a DC input voltage and a single-phase AC/AC converter. The single-phase AC/AC converter includes an AC inductor, a bus capacitor, a boost arm, a common arm and a buck arm. The method includes steps of: controlling the bus voltage to have a DC component and full-wave rectifying component, and setting a bus voltage parameter K so that the bus voltage approaches to a full-wave rectifying voltage when K approaches to 1, wherein 0≦K≦1.