A liner for a shaped charge is disclosed which comprises a plurality of portions, where at least one portion is composed of powder materials. In one embodiment, the liner comprises two portions that are composed of different powder materials, while alternative embodiments of the liner comprise three portions or four portions. When the shaped charge is used in a perforating gun, reactive powder materials may be added to the plurality of portions of the liner to optimize the penetration or the enhancement of the perforating tunnel.