A system and method for setting an ad-hoc network in a terminal are provided. The system includes a storage unit for storing a critical value of acceleration of the terminal, an acceleration sensor for measuring the acceleration of the terminal to provide a value of the measured acceleration, and a transmission frame processor for controlling transmission of a Media Access Control (MAC) frame for setting the network depending on whether the value of the acceleration measured by the acceleration sensor exceeds the critical value of acceleration pre-stored in the storage unit. The system performs Radio Frequency (RF) control on the terminals, each of which must operate as a host and a router in the ad-hoc network, using the acceleration sensor, thereby preventing use of unnecessary resources and reducing an amount of unnecessarily broadcast frames.