A printing apparatus is capable of forming images by overlappingly performing print processes for a plurality of colors with non-aqueous inks and an aqueous ink. When printing with the aqueous ink, it is possible to inhibit paper from being deformed and to realize a high density print process with a low see-through density. At least one of the plurality of colors is printed with a non-aqueous ink containing a water-insoluble solvent, and the remaining colors is printed with an aqueous ink containing a water-soluble solvent. The print process of the non-aqueous ink is performed in advance of the print process of the aqueous ink.