Semi-conductive silicone compositions and articles of manufacture containing these compositions are formed by combining a silicone precursor composition with an alkali metal salt and polymerizing the silicone precursor composition in the presence of the alkali metal salt to form a polymerized semi-conductive silicone composition. The polymerized silicone composition can be formed into a solid or foam article of manufacture having a volume resistivity of E8 to E12 ohm-cm, such as a roller or an anti-static belt.