发明授权
US08242237B2 Phase separator and monomer recycle for supercritical polymerization process 有权
用于超临界聚合过程的相分离器和单体循环

Phase separator and monomer recycle for supercritical polymerization process
摘要:
A process for polymerizing olefins, comprising the steps of: (a) contacting in a dense-fluid-homogeneous-polymerization system (“PS”), >30 wt % C3+ olefins with: catalyst, activator, 0-50 mol % comonomer, and 0-40 wt % diluent/solvent, at a temperature > PS Tc and a pressure no lower than 1 MPa below the PS cloud point pressure and the polymer or above 80° C., whichever is higher; (f) separating the monomer-rich phase from the polymer-rich phase; (g) recycling the separated monomer-rich phase and recovering polymer from the polymer-rich phase.
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