发明授权
US08242237B2 Phase separator and monomer recycle for supercritical polymerization process
有权
用于超临界聚合过程的相分离器和单体循环
- 专利标题: Phase separator and monomer recycle for supercritical polymerization process
- 专利标题(中): 用于超临界聚合过程的相分离器和单体循环
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申请号: US11854936申请日: 2007-09-13
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公开(公告)号: US08242237B2公开(公告)日: 2012-08-14
- 发明人: Chris B. Friedersdorf , Patrick Brant , Gabor Kiss
- 申请人: Chris B. Friedersdorf , Patrick Brant , Gabor Kiss
- 申请人地址: US TX Houston
- 专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人地址: US TX Houston
- 主分类号: C08F6/26
- IPC分类号: C08F6/26 ; C08F10/06
摘要:
A process for polymerizing olefins, comprising the steps of: (a) contacting in a dense-fluid-homogeneous-polymerization system (“PS”), >30 wt % C3+ olefins with: catalyst, activator, 0-50 mol % comonomer, and 0-40 wt % diluent/solvent, at a temperature > PS Tc and a pressure no lower than 1 MPa below the PS cloud point pressure and the polymer or above 80° C., whichever is higher; (f) separating the monomer-rich phase from the polymer-rich phase; (g) recycling the separated monomer-rich phase and recovering polymer from the polymer-rich phase.
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