发明授权
- 专利标题: Preparation of supported chromium catalyst and polymerization process
- 专利标题(中): 负载型铬催化剂的制备及聚合工艺
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申请号: US12012038申请日: 2008-01-31
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公开(公告)号: US08258246B2公开(公告)日: 2012-09-04
- 发明人: Ricky McCormick , David Knoeppel
- 申请人: Ricky McCormick , David Knoeppel
- 申请人地址: US TX Houston
- 专利权人: Fina Technology, Inc.
- 当前专利权人: Fina Technology, Inc.
- 当前专利权人地址: US TX Houston
- 主分类号: C08F2/00
- IPC分类号: C08F2/00 ; C08F4/24 ; C08F210/00 ; C08F110/02
摘要:
A process for the preparation of a chromium-type supported olefin polymerization catalyst. A fluidized bed of support particles in an inert carrier gas is established. A chromium (III) compound is added to the fluidized support particles to provide a supported catalyst component. The supported catalyst component is activated to convert at least a portion of the chromium (III) to Chromium (VI). The chromium (III) containing particles may be recovered from the fluidized bed and then activated or they may be activated in the fluidized bed. Also the support particles can be treated in the fluidized bed with other treatment agents. The support particles may be pretreated with a solution of a boron treating agent prior to incorporation of the support in the fluidized bed.
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