Invention Grant
- Patent Title: Water-absorbing polymer structures based on renewable raw materials and process for their production by dehydration
- Patent Title (中): 基于可再生原料的吸水聚合物结构及其脱水生产工艺
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Application No.: US13029208Application Date: 2011-02-17
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Publication No.: US08258249B2Publication Date: 2012-09-04
- Inventor: Günther Bub , Jürgen Mosler , Franz-Felix Kuppinger , Andreas Sabbagh , Guido Stochniol , Jörg Sauer , Markus Winterberg , Udo Knippenberg , Günter Latoschinski , Franck Furno , Thorsten Schwärtzke , Jörg Leistner
- Applicant: Günther Bub , Jürgen Mosler , Franz-Felix Kuppinger , Andreas Sabbagh , Guido Stochniol , Jörg Sauer , Markus Winterberg , Udo Knippenberg , Günter Latoschinski , Franck Furno , Thorsten Schwärtzke , Jörg Leistner
- Applicant Address: DE Krefeld
- Assignee: Evonik Stockhausen GmbH
- Current Assignee: Evonik Stockhausen GmbH
- Current Assignee Address: DE Krefeld
- Agency: Smith Moore Leatherwood LLP
- Agent Philip P. McCann
- Priority: DE102006039205 20060822
- Main IPC: C08F220/06
- IPC: C08F220/06 ; C08L33/02

Abstract:
The present invention relates to superabsorbent polymer comprising acrylic acid made by the process comprising the steps of heating an aqueous glycerine solution to form glycerine; transporting the glycerine to the dehydration reactor; dehydrating the glycerine to an acrolein-comprising dehydration product; gas phase oxidating of the acrolein-comprising dehydration product to obtain an acrylic acid-comprising monomer gas; bringing into contact of the monomer gas with a quench agent to obtain an acrylic acid-comprising quench phase; working-up the quench phase to obtain an acrylic acid-comprising monomer phase; and polymerizing the acrylic acid-comprising monomer phase; wherein a plurality of gas bubbles is generated and wherein the dehydration occurs at least partially in the liquid phase. The superabsorbent polymer has certain properties for biodegradability and sustainability. Further, at least about 25% of the acrylic acid is based on glycerine. The superabsorbent polymer has a sustainability factor of at least about 80%.
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