发明授权
- 专利标题: Process for redissociating Michael adducts which are present in a liquid F and have been formed in the preparation of acrylic acid or esters thereof
- 专利标题(中): 存在于液体F中并在丙烯酸或其酯的制备中形成的迈克尔加合物的再分离方法
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申请号: US12634143申请日: 2009-12-09
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公开(公告)号: US08263802B2公开(公告)日: 2012-09-11
- 发明人: Volker Schliephake , Thorsten Friese , Klaus Bott , Michael Blechschmitt , Till Blum , Klaus Joachim Mueller-Engel
- 申请人: Volker Schliephake , Thorsten Friese , Klaus Bott , Michael Blechschmitt , Till Blum , Klaus Joachim Mueller-Engel
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 代理机构: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- 优先权: DE102008054587 20081212
- 主分类号: C07C265/00
- IPC分类号: C07C265/00
摘要:
A process for redissociating Michael adducts which are present in a liquid F with a proportion by weight of ≧10% by weight and have been formed in the preparation of acrylic acid or esters thereof in a redissociating apparatus which comprises a pump P, a separating column K with separating internals and a circulation heat exchanger UW, wherein, for the purpose of supplying the cleavage energy, the pump P sucks in bottoms liquid from the bottom space of the separating column K and, via the circulation heat exchanger UW, continually recycles it into the bottom space above the level of the bottoms liquid, and wherein the pump P is a radial circulation pump with an open impeller.
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