发明授权
- 专利标题: Universal grignard metathesis polymerization
- 专利标题(中): 通用格氏复分解聚合
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申请号: US11849229申请日: 2007-08-31
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公开(公告)号: US08288508B2公开(公告)日: 2012-10-16
- 发明人: Richard D. McCullough , Mihaela C. Iovu , Itaru Osaka
- 申请人: Richard D. McCullough , Mihaela C. Iovu , Itaru Osaka
- 申请人地址: US PA Pittsburgh
- 专利权人: Carnegie Mellon University
- 当前专利权人: Carnegie Mellon University
- 当前专利权人地址: US PA Pittsburgh
- 代理机构: Foley & Lardner LLP
- 主分类号: C08G61/00
- IPC分类号: C08G61/00
摘要:
Universal Grignard Metathesis (GRIM) reactions which provide access to conjugated polymers by GRIM methods. A method comprising: providing an unsaturated ring compound comprising at least two halogen ring substituents, providing an organomagnesium reagent comprising an organomagnesium component and a metal activation agent, combining the unsaturated ring compound with the reagent to form a second compound by metal-halogen exchange, wherein the metal activation agent activates the metal-halogen exchange, coupling the second compound to itself in an oligomerization or polymerization reaction. Metal activation agent can be lithium chloride. The process is commercially attractive and can be executed in good yields. Polyfluorenes, polypyrroles, and polythiophenes can be prepared for use in OLED, PLED, photovoltaic, transistor, antistatic coatings, and sensor applications.
公开/授权文献
- US20080146754A1 UNIVERSAL GIRNARD METATHESIS POLYMERIZATION 公开/授权日:2008-06-19
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