Provided is the following electro-conductive member for electrophotography. The electrical resistance of the member hardly increases even by long-term energization, and hence the member is conducive to stable formation of high-quality electrophotographic images. The electro-conductive member for electrophotography, comprises: an electro-conductive mandrel and an electro-conductive layer, wherein said electro-conductive layer contains an A-B-A type triblock copolymer in which an A-block is a polystyrene having a cation exchange group, and a B-block is a polyolefin, and wherein said A-B-A type triblock copolymer forms a microphase-separated structure comprising a matrix phase formed of said B-block, and one phase formed of the A-block and having a structure selected from the group consisting of a cylindrical structure, a bicontinuous structure and a lamellar structure.