A display apparatus and a method for manufacturing an optical compound layer are provided. The display apparatus comprises a light source and an optical compound layer, wherein the light source is adapted to emit a light beam, and the light beam has a polarization direction. The optical compound layer is disposed on the light source correspondingly to receive the light beam. The optical compound layer comprises a thin film and a plurality of dopants doped therein. One of the thin film and the dopants has a specific orientation which is substantially the same as the polarization direction of the light beam and the refractive indexes of the thin film and the dopants are substantially the same as well.