发明授权
US08338631B2 Process for preparing dialkyl carbonates from alkylene carbonates and alcohols
有权
由碳酸亚烷基酯和醇制备碳酸二烷基酯的方法
- 专利标题: Process for preparing dialkyl carbonates from alkylene carbonates and alcohols
- 专利标题(中): 由碳酸亚烷基酯和醇制备碳酸二烷基酯的方法
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申请号: US12823470申请日: 2010-06-25
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公开(公告)号: US08338631B2公开(公告)日: 2012-12-25
- 发明人: Friedhelm Risse , Pieter Ooms , Andre Düx , Marcus Grünewald , Thomas Pancur , Arthur Susanto , Georg Ronge , Johan Vanden Eynde , Wim Wuytack
- 申请人: Friedhelm Risse , Pieter Ooms , Andre Düx , Marcus Grünewald , Thomas Pancur , Arthur Susanto , Georg Ronge , Johan Vanden Eynde , Wim Wuytack
- 申请人地址: DE Leverkusen
- 专利权人: Bayer MaterialScience AG
- 当前专利权人: Bayer MaterialScience AG
- 当前专利权人地址: DE Leverkusen
- 代理机构: Connolly Bove Lodge & Hutz LLP
- 优先权: DE102009030680 20090626
- 主分类号: C07C69/96
- IPC分类号: C07C69/96
摘要:
The present invention relates to a continuous process for preparing lower dialkyl carbonates as main product and alkylene glycol as by-product by catalyzed transesterification of a cyclic alkylene carbonate (e.g. ethylene carbonate or propylene carbonate) with lower alcohols, where the reaction of the alkylene carbonate is carried out with an alcohol containing dialkyl carbonate in countercurrent, characterized in that introduction of a stream containing at least 99.5% by weight of alcohol takes place below the point of introduction for the alcohol containing dialkyl carbonate in a particular spacing ratio between the abovementioned points of introduction.
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