发明授权
US08338631B2 Process for preparing dialkyl carbonates from alkylene carbonates and alcohols 有权
由碳酸亚烷基酯和醇制备碳酸二烷基酯的方法

Process for preparing dialkyl carbonates from alkylene carbonates and alcohols
摘要:
The present invention relates to a continuous process for preparing lower dialkyl carbonates as main product and alkylene glycol as by-product by catalyzed transesterification of a cyclic alkylene carbonate (e.g. ethylene carbonate or propylene carbonate) with lower alcohols, where the reaction of the alkylene carbonate is carried out with an alcohol containing dialkyl carbonate in countercurrent, characterized in that introduction of a stream containing at least 99.5% by weight of alcohol takes place below the point of introduction for the alcohol containing dialkyl carbonate in a particular spacing ratio between the abovementioned points of introduction.
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