The present invention relates to a process for stacking a high-power lithium battery, and the object of the present invention is to provide a process for stacking a high-power lithium battery, with lowered the error rate and minimized open circuit voltage drop of the battery. The process for stacking a high-power lithium battery according to the present invention is characterized by a process for preparing a lithium battery comprised of anodes (100), separators (300) and cathodes (200), which comprises the steps of a) providing the anode (100) attached to the separator (300); b) providing the cathode (200) attached to the separator (300); and c) alternately stacking the anodes (100) attached to the separator (300) and the cathodes (200) attached to the separator (300) to form a stack cell.