A method for converting heat to electricity by exploiting changes in spontaneous polarization that occur in electrically polarizable materials is described. The method uses an internally generated field to achieve poling during cycling. The internal poling field is produced by retaining residual free charges on the electrodes at the appropriate point of each cycle. The method obviates the need for applying a DC voltage during cycling and permits the use of the electrical energy that occurs during poling rather than an external poling voltage which detracts from the net energy produced per cycle. The method is not limited to a specific thermodynamic cycle and can be used with any thermodynamic cycle for converting heat to electricity by thermally cycling electrically polarizable materials. The electrical energy generated can be used in various applications or stored for later use. An apparatus for converting heat to electricity is also described.