A connection structure of an armature and a pushing mechanism of a relay has an armature and a pushing block. The head of the armature is T-shaped and connected by a vertical arm and a cross arm. One end of the pushing block has a bar-shaped through hole and a bar-shaped blind hole, disposed alongside and vertical to the motion direction of the pushing block. A through groove to connect the bar-shaped trough hole and the blind hole is disposed at the centre of the bar-shaped through hole and the blind hole. With the through groove, the T-shaped armature head can move along the through groove when the T-shaped armature head is shoved into the bar-shaped through hole. The cross arm of the T-shaped armature head is dropped into the bar-shaped blind hole to cooperate with the bar-shaped blind hole to drive the pushing block when the armature swings.