发明授权
- 专利标题: Continuous process for the production of a superabsorbent polymer
- 专利标题(中): 用于生产超吸收性聚合物的连续方法
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申请号: US12575071申请日: 2009-10-07
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公开(公告)号: US08357766B2公开(公告)日: 2013-01-22
- 发明人: Daniel Fricker , Herbert Gartner , Marc Hager , Jörg Harren , Hans-Peter Kohler , Harald Plöchinger
- 申请人: Daniel Fricker , Herbert Gartner , Marc Hager , Jörg Harren , Hans-Peter Kohler , Harald Plöchinger
- 申请人地址: DE Krefeld
- 专利权人: Evonik Stockhausen GmbH
- 当前专利权人: Evonik Stockhausen GmbH
- 当前专利权人地址: DE Krefeld
- 代理机构: Smith Moore Leatherwood LLP
- 代理商 Philip P. McCann
- 主分类号: C08F222/02
- IPC分类号: C08F222/02
摘要:
The present invention relates to a continuous process for the production of a superabsorbent polymer comprising providing an acidic liquid aqueous monomer mixture containing dissolved oxygen; continuously feeding the aqueous monomer mixture to a reactor; introducing a source of carbonate or hydrogen carbonate into the aqueous monomer mixture prior to entry into the reactor thereby forming a gas phase comprising carbon dioxide and at least a part of the dissolved oxygen, the gas phase being dispersed in the liquid phase; subjecting the gas/liquid mixture to at least partial phase separation immediately prior to or after entry into the reactor and at least partially removing the separated gaseous phase; subjecting the liquid phase in the reactor to free-radical polymerization to obtain the superabsorbent polymer, and continuously removing the superabsorbent polymer from the reactor.
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