发明授权
- 专利标题: Methods to produce 3,3,3-trifluoropropene
- 专利标题(中): 制备3,3,3-三氟丙烯的方法
-
申请号: US12875170申请日: 2010-09-03
-
公开(公告)号: US08373010B2公开(公告)日: 2013-02-12
- 发明人: Daniel C. Merkel , Konstantin A. Pokrovski , Hsueh Sung Tung , Selma Bektesevic
- 申请人: Daniel C. Merkel , Konstantin A. Pokrovski , Hsueh Sung Tung , Selma Bektesevic
- 申请人地址: US NJ Morristown
- 专利权人: Honeywell International Inc.
- 当前专利权人: Honeywell International Inc.
- 当前专利权人地址: US NJ Morristown
- 代理商 Bruce O. Bradford
- 主分类号: C07C17/25
- IPC分类号: C07C17/25
摘要:
Disclosed is a process for the preparation of 3,3,3-trifluoropropene comprising the steps of; (1) fluorination of 240fa to form 245fa; (2) conversion of 245fa to a cis/trans mixture of 1234ze; (3) hydrogenation of the cis/trans mixture of 1234ze to form 254fb ; and (4) dehydrofluorination of 254fb to produce 3,3,3-trifluoropropene. Alternatively or additionally, a second process for the preparation of the desired compound comprises the following steps; (1) fluorination of HCC-240fa to form HCFC-244fa; (2) conversion of 244fa to a cis/trans mixture of HFO-1234ze; (3) hydrogenation of the cis/trans mixture of 1234ze to form HFC-254fb; and (4) dehydrofluorination of 254fb to produce 3,3,3-trifluoropropene.
公开/授权文献
- US20120059201A1 METHODS TO PRODUCE 3,3,3-TRIFLUOROPROPENE 公开/授权日:2012-03-08
信息查询